بررسی اثر شکل جداکننده‌های بین آند و کاتد در باتری Al-AgO بر روی هیدرودینامیک جریان الکترولیت آن

نوع مقاله : مقاله پژوهشی

نویسندگان

1 دانشجوی دکتری، دانشگاه جامع امام حسین (ع) ، تهران ، ایران

2 کارشناسی ارشد ، دانشگاه شهید بهشتی ، تهران، ایران

چکیده

باتری‌های الکتروشیمیایی جریانی همچون باتری Al-AgO ، از جمله باتری‌های با ظرفیت بالا هستند که در آن‌ها الکترولیت بین صفحات آند و کاتد جریان داشته و سلول باتری در مسیر یک سیستم چرخشی بسته قرار دارد. با توجه به سنگین بودن اینگونه باتری‌ها، تلاش‌هایی در جهت کاهش حجم و وزن آن‌ها تاکنون انجام شده و معمولا فاصله بین آند و کاتد در حداقل مقدار تنظیم می‌شود. از طرفی نزدیک شدن بیش از حد آند و کاتد، خطر اتصال کوتاه داخلی در باتری را افزایش می‌دهد. بنابراین از جداکننده‌هایی بین صفحات آند و کاتد استفاده شده که مانع از برخورد آن‌ها با یکدیگر شوند. جداکننده‌ها با وجود جلوگیری از اتصال کوتاه، در مسیر جریان الکترولیت قرار داشته و مانع از حرکت مطلوب آن بین صفحات آند و کاتد می‌شوند. دنباله جریان ناشی از ممانعت آن‌ها بر مسیر جریان، از سطح فعال واکنش می‌کاهد و این رخداد باعث کاهش عملکرد و بازده باتری می گردد. به همین منظور در بررسی عددی حاضر، جریان الکترولیت در سل باتری بصورت تک‌فاز و پایا در نظر گرفته شده و بر روی اثر تعداد و نحوه چینش جداکننده‌ها با چهار شکل سطح مقطع دایره، مربع، لوزی و مثلث مطالعه و سطح فعال واکنش در هر یک بررسی شده است

کلیدواژه‌ها


عنوان مقاله [English]

The Effect Of Anode And Cathode Separators In Al-Ago Battery On The Hydrodynamic Of Electrolyte

نویسندگان [English]

  • Saeed Nahidi 1
  • Ehsan Behroozizade 2
1 PhD student, Imam Hossein University, Tehran, Iran
2 Master's degree, Shahid Beheshti University, Tehran, Iran
چکیده [English]

Flow electrochemical batteries such as Al-Ago Batteries are high-capacity batteries that the electrolyte flows between the anode and cathode plates and the battery cell is in a close system. Due to the heaviness of such batteries, efforts are done to reduce their volume and weight so the distance between the anode and cathode is minimized. On the other hand, being to close to the anode and cathode increase the risk of short-circuit the battery. So, separators between the anode and cathode were used to prevent them from touch each other. Although preventing short-circuit, the separators are located in the direction of the electrolyte flow, preventing the desired flow between the anode and cathode plates. The flow wake due to their obstruction on the flow path affects the active area of the reaction and thereby reduces battery efficiency. On the other hand, the cross-section shape of these separators has a great influence on the hydrodynamics of the electrolyte, wake length and the active area of the reaction. In the present study, the electrolyte is considered as single-phase, steady and the effect of the number and arrangement of the separators are studied for four shapes of circle, square, Lozenge and triangle cross-sections on the electrolyte flow and the active area of the reaction

کلیدواژه‌ها [English]

  • Al-Ago Flow Battery
  • Anode and Cathode Seprator
  • Wake
  • Electrochemical active area

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